Next generation batteries that use new electrolyte materials could achieve far higher energy density than today's lithium-ion batteries, without many of the safety concerns. But advanced batteries, such as those that use solid or almost-solid electrolytes, have been plagued by the formation of tiny spikes of lithium metal called dendrites that cause the batteries to lose efficiency and fail. Exactly how those dendrites form is still up for debate. While the interface between the battery's electrolyte and electrodes has been the focus of most research, another culprit is the boundary where two grains of electrolyte in a solid material meet. Researchers know these boundaries can seed dendrites within electrolytes, although the effects have been difficult to study. Now researchers at MIT and the Technical University of Munich have uncovered why such boundaries can lead to dendrites: Hidden electrical imbalances across the boundaries affect how the electrolyte conducts electrical...
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